Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ3 O,N,O′}cadmium
نویسنده
چکیده
The centrosymmetric title compound, [Cd(C(9)H(9)BrNO(2))(2)], was obtained by the reaction of 5-bromo-salicyl-aldehyde, 2-amino-ethanol and cadmium nitrate in ethanol. The Cd atom, located on an inversion centre, is hexa-coordinated by two Schiff base ligands in an octa-hedral coordination through the phenolate O atom, the imine N atom and the hy-droxy O atoms. In the crystal, mol-ecules are linked through inter-molecular O-H⋯O hydrogen bonds, forming chains along the b axis.
منابع مشابه
Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato}nickel(II) monohydrate
The title mononuclear nickel complex, [Ni(C(9)H(9)BrNO(2))(2)]·H(2)O, was obtained by the reaction of 5-bromo-salicyl-aldehyde, 2-amino-ethanol and nickel nitrate in methanol. The Ni(II) atom is six-coordinated by two phenolate O, two imine N and two hy-droxy O atoms from two crystallographically different Schiff base ligands, forming an octa-hedral geometry. In the crystal, mol-ecules are link...
متن کامل{4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ3 S,N,O}(triphenylphosphane-κP)nickel(II)
The Ni(II) atom in the title complex, [Ni(C(13)H(8)BrNOS)(C(18)H(15)P)], is coordinated by the N, O and S atoms of the dianionic tridentate ligand, and its square-planar geometry is completed by a phosphane P atom. The dihedral angle between the aromatic rings in the 4-bromo-2-[(2-sulfido-phen-yl)imino-meth-yl]phenolate ligand is 2.01 (14)°. The most prominent feature of the packing is the pres...
متن کامل{4-Chloro-2-[(2-hydroxyethyl)iminomethyl]phenolato}{4-chloro-2-[(2-oxidoethyl)iminomethyl]phenolato}cobalt(III)
In the title mononuclear cobalt(III) compound, [Co(C(9)H(8)ClNO(2))(C(9)H(9)ClNO(2))], the Co(II) atom is six-coordinated by two imine N atoms, two phenolate O atoms, and one hy-droxy and one oxide O atom from two Schiff base ligands, forming an octa-hedral geometry. In the crystal structure, adjacent mol-ecules are linked through inter-molecular O-H⋯O hydrogen bonds. The 2-oxidoethyl group is ...
متن کاملBis{4-chloro-2-[(2-hydroxyethyl)iminomethyl]phenolato}nickel(II) monohydrate
The title mononuclear nickel(II) complex, [Ni(C(9)H(9)ClNO(2))(2)]·H(2)O, was obtained by the reaction of 5-chloro-salicyl-aldehyde, 2-amino-ethanol and nickel nitrate in methanol. The Ni atom is six-coordinated by two phenolate O, two imine N and two hy-droxy O atoms from two crystallographically different Schiff base ligands, forming an octa-hedral geometry. In the crystal, mol-ecules are lin...
متن کاملBis{(E)-4-bromo-2-[(2-chloro-3-pyridyl)iminomethyl]phenolato-κ2 N,O}copper(II)
In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra-coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment. The inter-planar dihedral angles between the benzene and pyridi...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011